Year

2018

Type(s)

Journal Article

Author(s)

Torres Delgado, W. and Braun, C.A. and Boone, M.P. and Shynkaruk, O. and Qi, Y. and McDonald, R. and Ferguson, M.J. and Data, P. and Almeida, S.K.C. and Aguiar, I.D. and De Souza, G.L.C. and Brown, A. and He, G. and Rivard, E.

Source

ACS Applied Materials and Interfaces, 10(15): 12124—12134, 2018

Url

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85045620494&doi=10.1021%2facsami.7b11628&partnerID=40&md5=1d316cdaa6b7252f7834a7440495727d

BibTeX

BibTeX

BibTeX

@ARTICLE{TorresDelgado201812124, author={Torres Delgado, W. and Braun, C.A. and Boone, M.P. and Shynkaruk, O. and Qi, Y. and McDonald, R. and Ferguson, M.J. and Data, P. and Almeida, S.K.C. and Aguiar, I.D. and De Souza, G.L.C. and Brown, A. and He, G. and Rivard, E.}, title={Moving beyond Boron-Based Substituents to Achieve Phosphorescence in Tellurophenes}, journal={ACS Applied Materials and Interfaces}, year={2018}, volume={10}, number={15}, pages={12124-12134}, doi={10.1021/acsami.7b11628}, note={cited By 17}, url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-85045620494&doi=10.1021%2facsami.7b11628&partnerID=40&md5=1d316cdaa6b7252f7834a7440495727d}, affiliation={Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, AB T6G 2G2, Canada; Department of Physics, Durham University, Durham, DH1 3LE, United Kingdom; Faculty of Chemistry, Silesian University of Technology, Strzody 9, Gliwice, 44-100, Poland; Departamento de Química, Universidade Federal de Mato Grosso, Cuiabá, Mato Grosso, 78060-900, Brazil; Center for Materials Chemistry, Frontier Institute of Science and Technology, Xi'An Jiaotong University, Xi'an, Shaanxi, 710054, China}, abstract={Previous research in our group showed that tellurophenes with pinacolboronate (BPin) units at the 2- and/or 5-positions displayed efficient phosphorescence in the solid state, both in the presence of oxygen and water. In this current study, we show that luminescence from a tellurophene is possible when various aryl-based substituents are present, thus greatly expanding the family of known (and potentially accessible) Te-based phosphors. Moreover, for the green phosphorescent perborylated tellurium heterocycle, 2,3,4,5-TeC4BPin4 (4BTe), oxygen-mediated quenching of phosphorescence is an important contributor to the lack of emission in solution (when exposed to air); thus, this system displays aggregation-enhanced emission (AEE). These discoveries should facilitate the future design of color tunable tellurium-based luminogens. © 2017 American Chemical Society.}, keywords={Boron; Oxygen; Tellurium; Tellurium compounds, Color tunable; Enhanced Emission; Exposed to; Future designs; Heterocycles; System displays; Tellurophene; Tellurophenes, Phosphorescence}, funding_details={Conselho Nacional de Desenvolvimento Científico e TecnológicoConselho Nacional de Desenvolvimento Científico e Tecnológico, CNPq, 400179/2014-8}, funding_details={Killam TrustsKillam Trusts, Killam}, funding_details={Canada Foundation for InnovationCanada Foundation for Innovation}, funding_details={Conselho Nacional de Desenvolvimento Científico e TecnológicoConselho Nacional de Desenvolvimento Científico e Tecnológico, CNPq}, funding_details={Alexander von Humboldt-StiftungAlexander von Humboldt-Stiftung}, funding_details={Natural Sciences and Engineering Research Council of CanadaNatural Sciences and Engineering Research Council of Canada}, funding_details={691684}, funding_text 1={This work was supported by the Natural Sciences and Engineering Research Council (NSERC) of Canada (Discovery and CREATE grants to E.R., Discovery grant to A.B., postgraduate scholarship to C.A.B.); the Conselho Nacional de Desenvolvimento Cientifí co e Tecnologicó (CNPq) of Brazil (Special visiting researcher grant 400179/2014-8 to G.L.C.S. and A.B.); the Canada Foundation for Innovation (E.R.). M.P.B. acknowledges the Killam Trust for a Postdoctoral Fellowship. We thank Compute Canada for access to computational resources. We are also grateful to Prof. Yu Fang (Key Laboratory of Applied Surface and Colloid Chemistry, Shaanxi Normal University) for his assistance with the luminescence measurements. P.D. also thanks the European Union’s Horizon 2020 research and innovation program under grant agreement No. 691684. E.R. also thanks the Alexander von Humboldt Foundation for an Experienced Researcher Fellowship.}, references={Parke, S.M., Boone, M.P., Rivard, E., Marriage of Heavy Main Group Elements with π-Conjugated Materials for Optoelectronic Applications (2016) Chem. Commun., 52, pp. 9485-9505; Chivers, T., Laitinen, R.S., Tellurium: A Maverick among the Chalcogens (2015) Chem. Soc. 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Chem., 75, pp. 6244-6251}, correspondence_address1={Brown, A.; Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Canada; email: alex.brown@ualberta.ca}, publisher={American Chemical Society}, issn={19448244}, language={English}, abbrev_source_title={ACS Appl. Mater. Interfaces}, document_type={Article}, source={Scopus},