Year

2018

Type(s)

Journal Article

Author(s)

Pander, P. and Swist, A. and Turczyn, R. and Pouget, S. and Djurado, D. and Lazauskas, A. and Pashazadeh, R. and Grazulevicius, J.V. and Motyka, R. and Klimash, A. and Skabara, P.J. and Data, P. and Soloducho, J. and Dias, F.B.

Source

Journal of Physical Chemistry C, 122(43): 24958—24966, 2018

Url

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85056127476&doi=10.1021%2facs.jpcc.8b08329&partnerID=40&md5=e690934fa11e26b418f6786355927cb2

BibTeX

BibTeX

BibTeX

@ARTICLE{Pander201824958, author={Pander, P. and Swist, A. and Turczyn, R. and Pouget, S. and Djurado, D. and Lazauskas, A. and Pashazadeh, R. and Grazulevicius, J.V. and Motyka, R. and Klimash, A. and Skabara, P.J. and Data, P. and Soloducho, J. and Dias, F.B.}, title={Observation of Dual Room Temperature Fluorescence-Phosphorescence in Air, in the Crystal Form of a Thianthrene Derivative}, journal={Journal of Physical Chemistry C}, year={2018}, volume={122}, number={43}, pages={24958-24966}, doi={10.1021/acs.jpcc.8b08329}, note={cited By 7}, url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-85056127476&doi=10.1021%2facs.jpcc.8b08329&partnerID=40&md5=e690934fa11e26b418f6786355927cb2}, affiliation={Department of Physics, University of Durham, South Road, Durham, DH1 3LE, United Kingdom; Faculty of Chemistry, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, Wroclaw, 50-370, Poland; Institute of Materials Science, Kaunas University of Technology, K. Baršausko Str. 59, Kaunas, LT-51423, Lithuania; Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilenu pl. 19, Kaunas, LT-50254, Lithuania; Faculty of Chemistry, Silesian University of Technology, M. Strzody 9, Gliwice, 44-100, Poland; Université Grenoble Alpes, CNRS, INAC/SyMMES/MEM, CEA Grenoble, 17 rue des Martyrs, Grenoble, Cedex 9, 38054, France; WestCHEM, University of Glasgow, School of Chemistry, Joseph Black Building, University Avenue, Glasgow, G12 8QQ, United Kingdom}, abstract={Thianthrenes have been nearly forgotten as phosphors in recent years, but are now coming back, showing their strong potential in luminescent applications. Here, we present a comprehensive photophysical study of a carbazolyl derivative of thianthrene in different matrices and environments. The diffusion of oxygen is slowed down in the rigid environment of thianthrene organic crystals, suppressing their phosphorescence quenching.Triplet-triplet annihilation is also not significantly active in these systems. Both conditions facilitate the observation of simultaneous fluorescence and phosphorescence emissions at room temperature, in air, giving origin to strong white luminescence. Moreover, the color coordinates of the dual fluorescence-phosphorescence white emission, which is observed only in rigid amorphous media and in crystals, can be tuned. Copyright © 2018 American Chemical Society.}, keywords={Fluorescence, Carbazolyl derivatives; Color coordinates; Diffusion of oxygens; Dual fluorescence; Organic crystal; Photophysical studies; Rigid environment; White luminescence, Phosphorescence}, funding_details={European CommissionEuropean Commission, EC}, funding_text 1={P.P., R.P., and A.K. thank the European Union for financial support from EU’s Horizon 2020 for funding the EXCILIGHT project under Grant Agreement No. 674990. R.T. acknowledges the EU’s Horizon 2020 for funding the ORZEL project under Grant Agreement No. 691684.}, references={Pander, P., Swist, A., Soloducho, J., Dias, F.B., Room Temperature Phosphorescence Lifetime and Spectrum Tuning of Substituted Thianthrenes (2017) Dyes Pigm., 142, pp. 315-322; Liu, H., Gao, Y., Cao, J., Li, T., Wen, Y., Ge, Y., Zhang, L., Yang, B., Efficient Room-Temperature Phosphorescence Based on a Pure Organic Sulfur-Containing Heterocycle: Folding-Induced Spin-orbit Coupling Enhancement (2018) Mater. Chem. Front., 2, pp. 1853-1858; Pander, P., Data, P., Turczyn, R., Lapkowski, M., Swist, A., Soloducho, J., Monkman, A.P., Synthesis and Characterization of Chalcogenophene-Based Monomers with Pyridine Acceptor Unit (2016) Electrochim. Acta, 210, pp. 773-782; Pander, P., Motyka, R., Zassowski, P., Lapkowski, M., Swist, A., Data, P., Electrochromic Properties of Novel Selenophene and Tellurophene Derivatives Based on Carbazole and Triphenylamine Core (2017) J. Phys. 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