Year

2016

Type(s)

Journal Article

Author(s)

Pander, P. and Data, P. and Turczyn, R. and Lapkowski, M. and Swist, A. and Soloducho, J. and Monkman, A.P.

Source

Electrochimica Acta, 210: 773—782, 2016

Url

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84974733610&doi=10.1016%2fj.electacta.2016.05.185&partnerID=40&md5=30d1646e56bae7e8a9844b8338823bca

BibTeX

BibTeX

BibTeX

@ARTICLE{Pander2016773, author={Pander, P. and Data, P. and Turczyn, R. and Lapkowski, M. and Swist, A. and Soloducho, J. and Monkman, A.P.}, title={Synthesis and characterization of chalcogenophene-based monomers with pyridine acceptor unit}, journal={Electrochimica Acta}, year={2016}, volume={210}, pages={773-782}, doi={10.1016/j.electacta.2016.05.185}, note={cited By 13}, url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84974733610&doi=10.1016%2fj.electacta.2016.05.185&partnerID=40&md5=30d1646e56bae7e8a9844b8338823bca}, affiliation={Faculty of Chemistry, Silesian University of Technology, M. Strzody 9, Gliwice, 44-100, Poland; University of Durham, Physics Department, South Road, Durham, DH1 3LE, United Kingdom; Center of Polymer and Carbon Materials, Polish Academy of Sciences, M. Curie-Sklodowskiej 34, Zabrze, 41-819, Poland; Wroclaw University of Technology, Faculty of Chemistry, Wybrzeze Wyspianskiego 27, Wroclaw, 50-370, Poland}, abstract={2,4,6-Trisubstituted pyridine derivatives with different electropolymerizable groups were investigated. It was shown that steric hindrance caused by bichalcogenophene substituents in the 2,6-positions of pyridine enables successful electropolymerization whereas previous studies on 3,5-substituted pyridines shown difficulties caused by the presence of the pyridine nitrogen lone electron pair. Cyclic voltammetry and differential pulse voltammetry techniques were used to determine the electronic properties of the studied compounds and obtained polymers. UV-Vis-NIR and EPR spectroelectrochemistry were used to determinate the behavior of the polymers in the doping-dedoping cycles. The polymers were found to have coloration efficiency up to 245 cm2 C-1 and exhibit sufficient stability for application and highlighting their possible use as electroactive layers in electrochromic devices. © 2016 Elsevier Ltd. All rights reserved.}, author_keywords={EPR; pyridine; selenophene; thiophene; UV-Vis-NIR spectroelectrochemistry}, keywords={Cyclic voltammetry; Electronic properties; Electropolymerization; Infrared devices; Paramagnetic resonance; Polymers; Pyridine; Spectroelectrochemistry; Thiophene; Voltammetry, Coloration efficiencies; Differential pulse voltammetry techniques; Lone electron pair; Pyridine derivatives; Pyridine nitrogen; Selenophene; Synthesis and characterizations; UV-Vis NIR, Synthesis (chemical)}, funding_details={Narodowym Centrum NaukiNarodowym Centrum Nauki, NCN}, funding_text 1={This work was funded by a research grant no. 2011/03/B/ST5/01475 from National Science Centre, Poland .}, references={Winokur, M., Moon, Y.B., Heeger, A.J., Barker, J., Bott, D.C., Shirakawa, H., X-Ray Scattering from Sodium-Doped Polyacetylene: Incommensurate-Commensurate and Order-Disorder Transformations (1987) Phys. Rev. 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Acta, 128, pp. 430-438; Data, P., Kurowska, A., Pluczyk, S., Zassowski, P., Pander, P., Jedrysiak, R., Czwartosz, M., Monkman, A.P., Exciplex Enhancement as a Tool to Increase OLED Device Efficiency (2016) J. Phys. Chem., 120, pp. 2070-2078; Barth, M., Guilerez, S., Bidan, G., Bras, G., Lapkowski, M., Electrochemical investigation of regioregular alkyl substituted oligothiophenes (2000) Electrochim. Acta, 45, pp. 4409-4417; Sonmez, G., Meng, H., Wudl, F., Organic Polymeric Electrochromic Devices: Polychromism with Very High Coloration Efficiency (2004) Chem. Mater., 16, pp. 574-580; Patra, A., Bendikov, M., Chand, S., Poly(3,4-ethylenedioxyselenophene) and Its Derivatives: Novel Organic Electronic Materials (2014) Acc. Chem. Res., 47, pp. 1465-1474; Gerson, F., Huber, W., (2003) Electron Spin Resonance Spectroscopy of Organic Radicals, , Wiley-VCH Verlag GmbH & Co. KGaA Weinheim; Jahnke, A.C., Spulber, M., Neuburger, M., Palivan, C.G., Wenger, O.S., Electronic coupling mediated by furan, thiophene, selenophene and tellurophene in a homologous series of organic mixed valence compounds (2014) Chem. Commun., 50, p. 10883}, correspondence_address1={Data, P.; Faculty of Chemistry, Silesian University of Technology, M. Strzody 9, Poland; email: Przemyslaw.Data@polsl.pl}, publisher={Elsevier Ltd}, issn={00134686}, coden={ELCAA}, language={English}, abbrev_source_title={Electrochim Acta}, document_type={Article}, source={Scopus},