Year

2014

Type(s)

Journal Article

Author(s)

Olech, K. and Sołoducho, J. and Laba, K. and Data, P. and Lapkowski, M. and Roszak, S.

Source

Electrochimica Acta, 141: 349—356, 2014

Url

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84906271447&doi=10.1016%2fj.electacta.2014.07.084&partnerID=40&md5=6757547a693165965fe685baebc6519e

BibTeX

BibTeX

BibTeX

@ARTICLE{Olech2014349, author={Olech, K. and Sołoducho, J. and Laba, K. and Data, P. and Lapkowski, M. and Roszak, S.}, title={The synthesis and characterization of -3,4-ethylenedioxythiophene derivatives with electroactive features}, journal={Electrochimica Acta}, year={2014}, volume={141}, pages={349-356}, doi={10.1016/j.electacta.2014.07.084}, note={cited By 5}, url={https://www.scopus.com/inward/record.uri?eid=2-s2.0-84906271447&doi=10.1016%2fj.electacta.2014.07.084&partnerID=40&md5=6757547a693165965fe685baebc6519e}, affiliation={Wrocław University of Technology, Faculty of Chemistry, Wybrzeze Wyspiańskiego 27, 50-370 Wrocław, Poland; Centre of Polymer and Carbon Materials, Polish Academy of Sciences, M. Curie-Sklodowskiej 34, 41-819 Zabrze, Poland; Silesian University of Technology, Faculty of Chemistry, Strzody 9, 44-100 Gliwice, Poland}, abstract={We report the synthesis of conjugated oligomers based on electron withdrawing 3,4-ethylenedioxythiophene (EDOT) in the case of which band gaps are tuned by the insertion of alkylated diphenylamine or phenoxazine/phenothiazine units. The structures and properties of synthesized compounds were characterized by 1H NMR, 13C NMR, UV-Vis absorption, and fluorescence spectroscopy as well as electrochemical measurements. The luminescence spectra demonstrate that copolymers are good chromophores. Also the electrical properties confirm the applicability of these novel aryl-based π-conjugated oligomers for the development of various electrical and electrochemical devices. © 2014 Elsevier Ltd.}, author_keywords={3;4-ethylenedioxythiophene derivatives; cyclic voltammetry; gel permeation chromatography; molecular modeling; Suzuki condensation; UV-Vis spectroelectrochemistry}, keywords={Chromophores; Cyclic voltammetry; Fluorescence spectroscopy; Gel permeation chromatography; Molecular modeling; Nuclear magnetic resonance spectroscopy; Spectroelectrochemistry, 3 ,4 ethylenedioxythiophene (EDOT); Electrochemical devices; Electrochemical measurements; Luminescence spectrum; Structures and properties; Suzuki condensation; Synthesis and characterizations; UV-Vis spectroelectrochemistry, Oligomers}, funding_details={Narodowe Centrum NaukiNarodowe Centrum Nauki, NCN, 2012/05/B/ST5/00749}, funding_text 1={The financial support from the Wrocław University of Technology and NCN Grant No. 2012/05/B/ST5/00749 are gratefully acknowledged.}, references={Skotheim, T.A., Elsenbaumer, R.L., Reynolds, J.R., (1998) Handbook of Conducting Polymers: Second Edition, Revised and Expanded, , Marcel Dekker Inc New York; Roncali, J., Synthetic principles for bandgap control in linear pi-conjugated systems (1997) Chem. 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